SEMI OR FULLY CONTINUOUS PROCESS FOR PREPARATION OF POLYESTER BY TRANSESTERIFICATION POLYMERIZATION

摘要

Linear aromatic polyesters of bisphenols and dicarboxylic compounds are prepared by transesterification polymerization in either a semi-continuous process or in a fully continuous process wherein a first stage is conducted batchwise or continuously and a second stage is conducted continuously, wherein the second stage employs a wiped film reactor, optionally followed by a vented extrusion reactor. The polymerisation is preferably conducted in the presence of a catalyst in liquid form, and further under conditions wherein the catalyst is introduced concurrently with the introduction of liquid phase reactants to avoid substantial heating of the reactants in contact with the catalyst prior to onset of the transesterification reaction. The products of the processes have an unexpectedly low polydispersity.