发明名称 PHENOLIC RESIN FOR SHELL MOLDING AND ITS PRODUCTION
摘要 PURPOSE:To obtain the titled resin having low molecular weight and high welding temperature, curable quickly, and giving a cured product having high strength, by carrying out the novolak reaction of phenol with formaldehyde at a low molar ratio, dehydrating and dephenolating the product, and removing the dinucleus component. CONSTITUTION:(A) Phenol is made to react with (B) formaldehyde at a molar ratio (A/B) of 0.3-0.7 in the presence of an acidic catalyst to obtain a precondensate. The product is dehydrated and dephenolated, and the dinucleus component is removed by distilling the mixture in vacuum while introducing steam into the mixture when the reaction temperature reaches 180-200 deg.C, until the content of the dinucleus component and that of the high-molecular components having >=6 nuclei in the whole resin reach <=15wt% and <=55wt%, respectively. USE:Resin-coated sand for the casting mold, etc.
申请公布号 JPS60133017(A) 申请公布日期 1985.07.16
申请号 JP19830238859 申请日期 1983.12.20
申请人 DAINIPPON INK KAGAKU KOGYO KK 发明人 AKIBA MASATO;KUNITOMO HIDEO;OOTSUKA SHINJIROU;MATSUURA TADAYOSHI
分类号 C08G8/00;B22C1/22;C08G8/08 主分类号 C08G8/00
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