PROCESS FOR HEATING COAL OIL SLURRIES

摘要

PROCESS FOR HEATING COAL OIL SLURRIES Controlling gas to slurry volume ratio when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio. Controlling the gas to slurry volume ratio to achieve a gas holdup of about 0.4, and preferably 0.38, permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. Applicants have further discovered that at the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec-1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow (bubble, dispersed bubble, elongated bubble, and the like) to non-homogeneous flow (stratified, slugging, plug, and the like). Although applicants have observed stable operations with a maximum gas holdup as high as 0.72, applicants prefer to operate with a gas holdup no greater than 0.68.