发明名称 PROCESS FOR THE PREPARATION OF ETHERCARBOXYLATES
摘要 A process is disclosed for the preparation of ethercarboxylates by oxidation of etheralcohols, having the general formula of R-O-CH2CH2O)nH, where R represents an alkyl group having 8-22 carbon atoms, a phenyl group or an alkylphenyl group and n a whole number from 1-100, or mixtures of these etheralcohols, or by oxidation of oxyethylene-oxypropylene block copolymers having an average molecular weight of 1000-12000 and a content of 10-80% by weight ethylene oxide units, or mixtures of these copolymers. In this process a catalyst is used which, in adition to palladium, also contains platinum in a platinum : palladium weight ratio of between 0.1:1 and 5:1.
申请公布号 DE3262149(D1) 申请公布日期 1985.03.14
申请号 DE19823262149 申请日期 1982.08.25
申请人 STAMICARBON B.V. 发明人 DE MAN, HENDRIKUS CORNELIS J.;SPRONKEN, JOSEPHUS MARIE HUBERTUS
分类号 C07C59/125;B01J23/00;B01J23/40;C07B61/00;C07C51/00;C07C51/235;C07C67/00;C08G65/00;C08G65/32;C08G65/324;(IPC1-7):C07C59/68 主分类号 C07C59/125
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