| 摘要 |
The H2O2 oxidn. of alkanoic acids to peralkanoic acids was catalyzed by H2SO4, RSO3H(R=alkyl, aryl, aralkyl, alkaryl), H3PO4, acid phosphate esters, and MeCOCH(SO3H)CO2H. Thus, EtCO2H was treated with 70% H2O2 and 45% H2SO4 in ClCH2CHClMe at 39oC to yield EtC(0)OOH.
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