摘要 |
NEW MATERIAL:A compound of the formula (Rf is fluoroalkyl; R, R' are alkyl). EXAMPLE:Trifluoromethylsilylketene acetal. USE:A synthetic intermediate of physiologically active substances bearing fluoroalkyl groups. PREPARATION:The reaction of a fluoroester of the formula: RfCH2COOR' with a silylating agent of the formula: (R)3SiOTf (Tf is trifluoromethanesulfonyl) is effected to give the objective compound.
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