PERFLUORO CYCLIC AMINE COMPOUND

摘要

NEW MATERIAL:A compound, expressed by the formula (k and n are 1 or 2; land n are 0,1,2 or 3), which may be substituted at an optional position by a trifluoromethyl group. EXAMPLE:Perfluoro-2-azatricyclo[6.3.0.0<2>,<6>]undecane. USE:Useful as a blood substitute, oxygen transporting component in the oxygen transportation fluid therapy, etc., capable of dissolving a large amount of oxygen, metabolically inert, and excretive rapidly to the outside of the body. PROCESS:A perhydro compound which is a raw material compound is dissolved in anhydrous hydrogen fluoride in an electrolytic cell. The resultant solution is then electrolyzed at 4-8V, 0.1-10A/dm<2> anodic current density and 4-12 deg.C electrolytic temperature. A mixture solution of an aqueous solution of an alkali with an amine type compound are added thereto, and the fluorine compound is decomposed under refluxing and purified to give the aimed compound expressed by the formula.