| 摘要 |
A process for the production of a sulphinate of formula <IMAGE> (1) which comprises reacting a compound of formula <IMAGE> (2a) or <IMAGE> (2b) or a mixture of the compounds of formulae (2a) and (2b) with a compound of formula Y-SO2-M (3) in an organic solvent in the presence of a mineral acid or organic acid and, optionally, also of water, wherein Ar1 and Ar2 are the same or different and each represents an unsubstituted or substituted aromatic carbocyclic radical. R1, R2, R3 and R4 independently of one another represent hydrogen, C1-C12-alkyl, C2-C8-alkoxyalkyl, cycloalkyl, aralkyl, aryl, or substituted alkyl, cycloalkyl, aralkyl or aryl, or each of the pairs of substituents (R1 and R2) and (R3 and R4), together with the nitrogen atom to which said pair is attached, independently, represents a heterocyclic ring, or one of several of the substituents R1, R2, R3 and R4 with the nitrogen and an adajcent carbon atom of the residue Ar1 or Ar2 form a heterocyclic ring, Y represents an unsubstituted or substituted C1-C20-alkyl, cycloalkyl, aryl, aralkyl or heterocyclic radical, X represents oxygen, sulphur or imino, T1 and T2 independently represent hydrogen, C1-C12-alkyl, C2-C12-alkenyl, aryl, aralkyl, and T1 also amido or ureido, or T1 and T2 together with the nitrogen atom which links them represent a five or six-membered heterocyclic radical and M represents hydrogen, ammonium, an alkali metal or an alkali earth metal.
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