摘要 |
1,225,228. Ferrites. PHILIPS ELECTRONIC & ASSOCIATED INDUSTRIES Ltd. 4 Sept., 1969 [7 Sept., 1968], No. 43839/69. Heading C1A. [Also in Division H1] ] A polycrystalline magnetically anisotropic spinel ferrite body is made by mixing a crystallized ferrite having axial or planar crystal anisotropy and defined by the formula with an oxide A"O, shaping the mixture while magnetically orientating the individual crystals by magnetic and/or mechanical .means, And then sintering the shaped body. A<SP>II</SP>and B<SP>II</SP> are each one or more of Fe<SP>II</SP> Ni<SP>II</SP> Mn<SP>II</SP>, Co<SP>II</SP> Zn, Mg, Cu<SP>II</SP> and Li<SP>I</SP> + Fe<SP>III</SP>/2; and x is 6 or 8. At least part of the A<SP>II</SP>O may be replaced by one or more compounds convertible to A<SP>II</SP>O on heating, and part of the Fe<SP>III</SP> in the ferrite may be replaced by at least one of Al, Cr<SP>III</SP> and A<SP>II</SP> + M<SP>IV</SP>/2 where M<SP>IV</SP> is Ti<SP>IV</SP> and/or Sn<SP>IV</SP>. Magnetic orientation may be effected by application of a magnetic field or by incorporating a binder, rolling or extruding into strips or plates, and then burning of the binder before sintering. An example describes the preparation of nickel ferrites (NiFe 2 O 4 ) from PbFe 12 O 19 and NiO. |