| 摘要 |
1,197,847. Hydroformylation. UNION CARBIDE CORP. 17 July, 1968 [3 Aug., 1967], No. 33934/68. Heading C2C. A process for the production of oxygenated products rich in normal aldehydes which comprises contacting an alpha olefinic compound with CO and H 2 in the presence of a catalytic quantity of a complex catalyst consisting essentially of Rh in complex combination with CO and a ligand containing a triorgano substituted trivalent atom of an element selected from phosphorus, arsenic and antimony, each organo moiety being monovalently bonded to said trivalent atom through a carbon atom or an aliphatic etheric oxygen atom, said trivalent atom possessing one available pair of electrons, said ligand having a #HNP value of at least 425; and at least 2 mols. of free ligand as defined above being present per mol. of rhodium, at a temperature in the range of from 50‹ C.-145‹ C., at a total pressure of CO and H 2 of less than about 450 p.s.i.a., and the partial pressure attributable to CO being no greater than 75% of said total pressure, thereby reacting said alpha olefinic compound with said CO and H 2 with the formation of oxygenated products rich in normal aldehydes which have one more carbon atoms than said alpha olefinic compound. Preferred ligands include triphenyl phosphine and triphenyl phosphite. Olefinic starting material used in examples includes oct-1-ene, hex-1-ene, propylene, dodec-1- ene, methyl methacrylate, allyl acetate, 5- hexenamide, allyl ethyl ether and hex-1-en- 4-ol. |
