发明名称 PROCESS FOR CONVERTING A CHIRAL ACID ESTER OF AN OPTICALLY-ACTIVE A-CYANO SECONDARY ALCOHOL INTO A CHIRAL ACID ESTER OF A RACEMIC A-CYANO SECONDARY ALCOHOL
摘要 A process for the preparation of an ester of chiral (A) acid with a racemic (R,S) alpha -cyano-3-phenoxybenzyl alcohol (B) by reacting an ester of chiral (A) acid with alpha -cyano-3-phenoxybenzyl alcohol of the formula <IMAGE> B in its optically active (R) form or (S) form or a mixture of esters of said (R) alcohol and (S) alcohol in non-equimolecular proportions with a base selected from the group consisting of ammonia, primary, secondary and tertiary amines, quaternary ammonium compounds, liquid amines of high molecular weight and a catalytic amount of a strong base in at least one solvent for the starting esters and in which the ester of racemic alcohol is soluble and recovering from the resulting solution the ester of chiral (A) acid with racemic (R,S) alcohol.
申请公布号 ZA7702465(B) 申请公布日期 1978.06.28
申请号 ZA19770002465 申请日期 1977.04.25
申请人 ROUSSEL UCLAF 发明人 PROSTMARECHAL J;COSQUER P;WARNANT J
分类号 A01N53/08;A01N53/14;A01P13/00;C07B31/00;C07B55/00;C07C67/00;C07C69/743;C07C253/00;C07C253/30;C07C255/38;C07C255/39;C07C255/53 主分类号 A01N53/08
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