发明名称 |
Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts |
摘要 |
This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol. In one embodiment, the catalyst comprises a metal supporting structure (preferably a metal sponge supporting structure comprising at least about 10% by weight nickel) having a copper-containing active phase at the surface thereof and iron as a catalyst modifier. The supporting structure is resistant to deformation under the conditions of the dehydrogenation reaction. This invention is also directed to novel nickel-containing catalysts having a copper-containing active phase and iron as a catalyst modifier which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts. |
申请公布号 |
AU2002362929(A1) |
申请公布日期 |
2003.04.28 |
申请号 |
AU20020362929 |
申请日期 |
2002.10.16 |
申请人 |
MONSANTO TECHNOLOGY LLC |
发明人 |
ALLMAN JAMES M;MORGENSTERN DAVID A;COLEMAN JAMES P |
分类号 |
B01J23/70;B01J23/72;B01J23/745;B01J23/755;B01J25/02;B01J37/02;B01J37/16;B01J37/34;C07C51/235;C07C227/02;C07F9/38 |
主分类号 |
B01J23/70 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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