发明名称 |
PROCESS FOR PRODUCING 1,1,1,2,2-PENTAFLUOROETHANE, PROCESS FOR PRODUCING 2,2-DICHLORO-1,1,1-TRIFLUOROETHANE, AND METHOD OF PURIFYING 1,1,1,2,2-PENTAFLUOROETHANE |
摘要 |
<p>A process for producing HFC-125 by dividing the reaction system into a first reaction zone for the vapor-phase reaction of mainly perchloroethylene with HF in the presence of a catalyst and a second reaction zone for the vapor-phase reaction of HCFC-123 (CF3CHCl2) and/or HCFC-124 (CF3CFHCl) with HF in the presence of a catalyst, wherein the first reaction zone is kept under a high pressure while the second reaction zone is kept under a low pressure. This process serves to keep a high conversion of perchloroethylene and increase the selectivity of HFC-125 while retaining a catalyst life. A process for purifying HFC-125 by the reaction of a mixture composed of at least 85 vol. % of HFC-125 and at most 15 vol. % of CFC-115 with hydrogen in the presence of a catalyst. This process serves to moderate the reaction conditions, reduce the absolute amount of the by-products formed, and purify HFC-125 efficiently.</p> |
申请公布号 |
EP0687660(A1) |
申请公布日期 |
1995.12.20 |
申请号 |
EP19940908493 |
申请日期 |
1994.03.03 |
申请人 |
DAIKIN INDUSTRIES, LIMITED |
发明人 |
SHIBANUMA, TAKASHI, YODOGAWA WORKS OF;HOMOTO, YUKIO, YODOGAWA WORKS OF;KOMATSU, SATOSHI, YODOGAWA WORKS OF;YOSHIMURA, TOSHIKAZU, YODOGAWA WORKS OF |
分类号 |
C07C17/20;C07C17/21;C07C17/395;C07C19/08;(IPC1-7):C07C19/08;B01J23/46;B01J23/44;B01J23/28;B01J23/26;B01J23/14;B01J21/06;C07C17/38;B01J23/64;B01J23/22 |
主分类号 |
C07C17/20 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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