LIQUID PHASE PROCESS FOR THE POLYMERIZATION OF ALPHA-OLEFINS

摘要

A liquid-phase process for polymerizing alpha-olefins of the formula CH₂-CHR, where R is H or an alkyl radical C1-C6, to produce a polymer that is soluble in the reaction medium, comprising the steps of: a) continuously polymerizing in liquid phase the alpha-olefin in the presence of a catalyst system based on a transition metal compound; b) continuously withdrawing from step a) a solution of polymer in the liquid reaction medium; c) mixing in one or more mixing stages said solution of polymer in the reaction medium with an organic deactivator having: at least a hydroxy group, a boiling point higher than 150° C., and a ratio between the molecular weight (MW) and the number of hydroxy groups (OH) comprised between 20 and 100.