发明名称 Inorganic phosphor, manufacture thereof, light-emitting device, and image display utilizing inorganic phosphor
摘要 Provided is a chemically and thermally stable phosphor having different light-emitting characteristics than a conventional phosphor and having high light-emitting intensity even when combined with an LED of 410 nm or lower. The phosphor comprises an inorganic compound in which an inorganic crystal including A element, D element, X element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; and X is one or more elements selected from O, N, and F), and, if necessary, E element (where E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La) includes Li element and M element (where M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
申请公布号 US9617471(B2) 申请公布日期 2017.04.11
申请号 US201414786248 申请日期 2014.04.24
申请人 National Institute of Materials Science 发明人 Hirosaki Naoto;Takeda Takashi;Funahashi Shiro;Narimatsu Eiichirou
分类号 H01L33/00;C09K11/77;H01L33/50 主分类号 H01L33/00
代理机构 Trojan Law Offices 代理人 Trojan Law Offices
主权项 1. A phosphor comprising an inorganic compound in which an inorganic crystal including at least an A element, a D element, and an X element (where A is one or two or more elements selected from the group consisting of Mg, Ca, Sr, and Ba; D is one or two or more elements selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf; and X is one or two or more elements selected from the group consisting of O, N, and F), further, when necessary, an E element (where E is one or two or more elements selected from the group consisting of B, Al, Ga, In, Sc, Y, and La), and comprising any of (1) a crystal represented by A1 (D, E) 7X10; (2) a Sr1Si7N10 crystal or a crystal having a same crystal structure as the Sr1Si7N10 crystal; or (3) a Ba1Si7N10 crystal or a crystal having a same crystal structure as the Ba1Si7N10 crystal, and comprising a Li element and an M element (where M is one or two or more elements selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb,) wherein the inorganic crystal is represented by a composition formula LcMdAeDfEgXh (here, in the formula, c+d+e+f+g+h=1, L is the Li element) and parameters c, d, e, f, g, and h satisfy all conditions 0.001≦c≦0.7,0.00001≦d≦0.05,0.01≦e≦0.1,0.1≦f≦0.4,0≦g≦0.1, and0.15≦h≦0.65, wherein the inorganic compound emits white color fluorescence upon irradiation by an excitation source.
地址 Tsukuba-shi JP