Nickel composite hydroxide and production method thereof, cathode active material for a non-aqueous electrolyte secondary battery and production method thereof, and a nonaqueous electrolyte secondary battery

摘要

When producing a nickel composite hydroxide that is a precursor to the cathode active material for a non-aqueous electrolyte secondary battery by supplying an aqueous solution that includes at least a nickel salt, a neutralizing agent and a complexing agent into a reaction vessel while stirring and performing a crystallization reaction, a nickel composite hydroxide slurry is obtained while controlling the ratio of the average particle size per volume of secondary particles of nickel composite hydroxide that is generated inside the reaction vessel with respect to the average particle size per volume of secondary particles of nickel composite hydroxide that is finally obtained so as to be 0.2 to 0.6, after which, while keeping the amount of slurry constant and continuously removing only the liquid component, the crystallization reaction is continued until the average particle size per volume of secondary particles of the nickel composite hydroxide becomes 8.0 μm to 50.0 μm.

主权项

1. A production method for producing a nickel composite hydroxide as a precursor to a cathode active material for a non-aqueous electrolyte secondary battery;
the method producing the nickel composite hydroxide by supplying an aqueous solution including at least a nickel salt; a neutralizing agent; and an ammonium ion donor; to a reaction vessel while stirring, and performing a crystallization reaction, comprising:
a primary crystallization process of obtaining a nickel composite hydroxide slurry while performing control so that a ratio of an average particle size per volume (MV) of secondary particles of nickel hydroxide that are generated inside the reaction vessel with respect to an average particle size per volume (MV) of secondary particles of nickel composite hydroxide that will finally be obtained becomes 0.2 to 0.6; anda second crystallization process of continuing the crystallization reaction until the average particles size per volume (MV) of secondary particles of the nickel composite hydroxide becomes 9.0 μm to 50.0 μm, while at the same time maintaining an amount of the slurry obtained in the primary crystallization process and continually removing only a liquid component of the slurry.