发明名称 |
Production method for compound comprising amino group and/or hydroxyl group |
摘要 |
Disclosed is a method for producing a compound having an amino group and/or a hydroxyl group from a substrate compound having an atomic group containing CO or CS by eliminating such atomic group. The substrate compound, having an atomic group containing CO or CS (for example, an amide, a carbamate, or the like), is allowed to react with a compound expressed by formula (I) below, at a temperature of 120° C. or lower, preferably in the presence of an ammonium salt, to eliminate such atomic group containing CO or CS. In formula (I) A may not be present, and in a case where A is present, A represents an alkyl group having 1 to 6 carbon atoms.
H2N-A-NH2 (I). |
申请公布号 |
US9278905(B2) |
申请公布日期 |
2016.03.08 |
申请号 |
US201314382455 |
申请日期 |
2013.03.04 |
申请人 |
Kyushu University, National University Corporation |
发明人 |
Ohshima Takashi;Morimoto Hiroyuki;Shimizu Yuhei |
分类号 |
C07C211/00;C07C209/62;C07D217/02;C07B41/02;C07B43/04;C07B51/00;C07C213/02;C07C227/06;C07D209/16;C07F7/18;C07C41/26;C07C29/00;C07C41/18;C07C227/04;C07D209/08;C07D309/12;C07D317/28 |
主分类号 |
C07C211/00 |
代理机构 |
Fay Sharpe LLP |
代理人 |
Fay Sharpe LLP |
主权项 |
1. A method for producing a first compound having at least one of an amino group and a hydroxyl group from a substrate compound having an atomic group containing a carbonyl or thiocarbonyl group CX, wherein X represents an oxygen atom or a sulfur atom, the method comprising allowing said substrate compound to react with a second compound in the presence of an ammonium salt at a temperature of 120° C. or lower to eliminate said atomic group containing the CX from said substrate compound, said second compound being expressed by formula (I):
H2N-A-NH2 (I) wherein A represents:
a bond; oran unsubstituted alkylene group having 1 to 6 carbon atoms; ora substituted alkylene group, in which one or two of the carbon atoms of an unsubstituted alkylene group having 2 to 6 carbon atoms is each substituted with a nitrogen atom. |
地址 |
Fukuoka JP |