发明名称 |
CHIRALE DIPHOSPHONITE ALS LIGANDEN IN DER RUTHENIUM-KATALYSIERTEN ENANTIOSELEKTIVEN REDUKTION VON KETONEN, ß-KETOESTERN UND KETIMINEN |
摘要 |
<p>Chiral ruthenium complexes are disclosed, obtained by reaction of a ruthenium salt with a chiral diphosphonite. Chiral diols with the general structure given in scheme 1 are preferably used as chiral diphosphonites. Said ruthenium complexes can be simply and economically obtained and provide high enantioselectivity on reduction of ketones, beta-ketoesters and ketimines.</p> |
申请公布号 |
DE502006004310(D1) |
申请公布日期 |
2009.09.03 |
申请号 |
DE20065004310T |
申请日期 |
2006.05.30 |
申请人 |
STUDIENGESELLSCHAFT KOHLE MBH |
发明人 |
REETZ, MANFRED THEODOR;LI, XIAOGUANG |
分类号 |
C07F15/00;B01J31/12;C07B53/00;C07F9/6564;C07F9/6571;C07F9/6574 |
主分类号 |
C07F15/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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