发明名称 Method and composition for improving fuel combustion
摘要 A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
申请公布号 US8945244(B2) 申请公布日期 2015.02.03
申请号 US201213649274 申请日期 2012.10.11
申请人 发明人 Carroll Robert W.;Carroll Noel;Carroll William F.;Carroll Michael
分类号 C10L1/12;C10L10/00;B01J13/00;C10L1/10;C10L3/00;C10L10/02;C10L1/16;C10L1/18;C10L1/182;C10L1/185;C10L1/20;C10L1/26;C10L1/30 主分类号 C10L1/12
代理机构 Zarley Law Firm, P.L.C. 代理人 Zarley Law Firm, P.L.C.
主权项 1. A mixture comprising at least one combustion catalyst or enhancer and a suitable solvent selected from one or more of isopropyl alcohol, methanol, ethanol, ethylene glycol, MTBE, methylethylketone and methylisobutylketone, wherein the combustion catalyst or enhancer is present in an amount between 1 part by weight per 12 million parts of the mixture to 1 part by weight per 100 billion (100,000,000,000) parts of the mixture and wherein the one or more combustion catalysts or enhancers are at least one of ruthenium (IV) oxide, ruthenium (III) chloride, ruthenium (III) chloride trihydrate, ruthenium (III) bromide and its hydrates, ammonium aquopentachlororuthenium (III) (NH4) 2RuCl5.H2O, potassium ruthenium (VI) oxide, rhodium (III) oxide, rhodium (III) chloride and its hydrates, rhodium (III) nitrate and its hydrates, iridium (III) chloride, iridium (III) oxide, iridium (IV) oxide, hydrogen hexachloroiridium (IV) and its hydrates, ammonium hexachloroiridium (IV) and its hydrates, osmium tetroxide, osmium (III) chloride, platinum black, platinum (IV) oxide and its hydrates, platinum (II) chloride, platinum (IV) chloride, polyvinylchloride, ammonium nitrate, hydrogen hexachloroplatinum (IV) hydrate, hydrogen hexahydroxoplatinum (IV), potassium hexachloroplatinate (IV); hydrogen hexachloroplatinate (IV); tetraamineplatinum (II) chloride monohydrate, dinitritodiamineplatinum (II), dihydrogen sulphatodinitrito platinum (II), tetraamineplatinum (II) dinitrate, palladium (II) chloride, palladium (II) oxide, palladium (II) nitratedihydrate, ammonium hexachloropalladium (IV), tetraaminepalladium (II) nitrate, potassium tetracyanopalladium (II) trihydrate, potassium perrhenate, rhenium (III) chloride, tris (acetyl acetonate) rhenium (III), cis-Dichloro(2, 2′-bipyridine)platinum (II) PtC12 (C10H8N2), dichloro(1, 5-cyclooctadiene)platinum (II) PtC12(C8H12), 2-hydroxyethanethiolato(2,2′,2″-terpyridine)platinum (II) nitrate [Pt(C2H5OS) (C15H11N3)]NO3, tricarbonylchloroiridium (I), [IrCl(CO)3]n, chloro(1,5-cyclooctadiene)iridium (I) dimer [IrCl(C8H12)]2, trans-dichlorobis(ethylenediamine)iridium (III) chloride trans- [IrC12(C2H8N2)2]Cl, rhodium (II) octanoate dimer Rh2 [O2C(CH2)6CH3]4, acetylacetonato(1,5-cyclooctadiene) rhodium (I) Rh(C8H12) (C5H7O2) , acetylacetonato(norbornadiene) rhodium (I) Rh(C7H8) (C5H7O2), hydridotetrakis(triphenylphosphine) rhodium (I) RhH(PPh3)4, diacetatobis (triphenylphosphine)palladium (II) (CH3CO2)2Pd(PPh3)2, Bis(dibenzylideneacetone) palladium (0) Pd(C17H14O)2, Dichloro [1, 2-bis (diphenylphosphino) ethane] palladium (II) PdC12(Ph2PCH2CH2PPh2), Palladium (II) trifluoracetate Pd(CF3CO2)2, Acetatohydridotris(triphenylphosphine)ruthenium(II) RuH(OCOCH3)(PPh3)3, Bis(benzene)dichlorodi-chlorodiruthenium (II) [RuCl2(C6H6)2]2, Tris (2, 2′-bipyridine)ruthenium (0) (C10H8N2)3Ru, Carbonyldihydridotris(triphenylphosphine) ruthenium (II) RuH2(CO)(PPh3)3, Bis(cyclopentadienyl)ruthenium (II) “Ruthenocene” (C5H5)2Ru, Dihydridotetrakis(triphenylphosphine)ruthenium (II) RuH2(PPh3)4, Ruthenium(III)hexafluoroacetylacetonate Ru(CF3COCHCOCF3)3, Ammonium nitrate, Dichloroethylenediamineplatinum (II) [Pt(C2H8N2)Cl2], Bis(acetylacetonato)platinum (II) [Pt(C5H7O2)2], Dichlorobis(triphenylphosphine)platinum (II) [PtCl2(PPh3)2], Tetrakis (triphenylphosphine)platinum (0) [Pt(PPh3)4], Bis(acetylacetonato)palladium (II) [Pd(C5H7O2)2], Dichloro(cycloocta-1,5-diene)palladium (II) [Pd(C8H12)Cl2], Chloro(.pi.-allyl)palladium (II) dimer [Pd(.pi.—C3H5)Cl]2, Palladium (II) acetate trimer [Pd(CH3CO2)2]3, Tris (acetylacetonato)ruthenium (III) [Ru(C5H7O2)3], Hydridocarbonyltris (triphenylphosphine) rhodium (I) [Rh(H)(CO)(PPh3)3], Acetylacetonatodicarbonyirhodium (I) [Rh(CO)2(C5H7O2)], Tris(acetylacetonato)rhodium (III) [Rh(C5H7O2)3], Bromotris (triphenylphosphine) rhodium (I) [RhBr(PPh3)3], Rhodium (II) acetate dimer [Rh2(CO2CH3)4], Tris(acetylacetonato)iridium (III) [Ir(C5H7O2)3], Dodecacarbonyltriosmium (0) Os3(CO)12, Palladium (II) Chloride or the bromide, iodide, nitrate hydrate, oxide, sulfate hydrate and hydroxide; Tris (dibenzylideneacetone) dipalladium (0); Dichloro(1,1-bisdiphenylphosphino) ferrocenepalladium (II); Allylpalladium (II) Chloride Dimer; trans-Dichlorobis (acetonitrile)palladium (II); trans-Dichlorobis (benzonitrile)palladium (II); trans-Dichlorobis (triphenylphosphine)palladium (II); trans-Acetato (triphenylphosphine)palladium (II); Dichloro(norbornadiene)palladium (II); 2,4 n Pentanedionate Palladium (II); Platinum (II) Chloride; Platinum (IV) Chloride, or bromide, iodide and sulfide salts; Platinum (IV) Oxide Hydrate (Adam's Catalyst); 2,4 n Pentanedionate Platinum (II); Dibromo(1,5-cyclooctadiene)platinum (II); Diiodo(1,5-cyclooctadiene) platinum (II); Diphenyl(1,5-cyclooctadiene) platinum (II); Dichlorobis(acetonitrile)platinum (II); Dichlorobis(benzonitrile)platinum (II); Dichloro(norbornadiene)platinum (II); Dihydrogen Hexachloroplatinum (IV); Rhodium (III) Chloride Hydrate; Rhodium (III) Iodide, or oxide, sulfate or bromide salts; 2,4-Pentanedionate Rhodium (III); Dicarbonyl 2,4-Pentanedionate Rhodium (I); Chlorotris (triphenylphosphine)rhodium (I); Bromocarbonylbis (triphenylphosphine) rhodium (I); Chlorocarbonylbis (triphenylphosphine) rhodium (I); Chloro(norbornanediene)rhodium (I) Dimer; Bis(1,5-cyclooctadiene) rhodium (I) tetrafluoroborate; Ruthenium (III) Chloride Hydrate, or the oxide, bromide, iodide and amine salts; Dichlorotris(triphenylphosphine)ruthenium (II); Dichlorotricarbonylruthenium (II) Dimer; 2,4-Pentanedionate Ruthenium (III); Dichloro(1,5-cyclooctadiene)ruthenium (III) Oligomer; Dicarbonylbis(triphenylphosphine)ruthenium (II); Tri-ruthenium (0) Dodecacarbonyl; Ruthenium Nitrosylnitrate; Iridium (IV) Chloride Hydrate, iridium (III) chloride, oxide, hydroxide, bromide, sulfate or iodide salts; 2,4-Pentanedionate Iridium (III); 2,4-Pentanedionate Dicarbonyliridium (I); Chlorocarbonylbis (triphenylphosphine) iridium (I); Hydridocarbonyltris(triphenylphosphine)iridium (I); Bis (1,5-cyclooctadiene) iridium (I) tetrafluoroborate; Osmium (VIII) Oxide, the fluoride, chloride, bromide, sulfate, nitrate salts and hydrates in soluble form of the following metals: Lanthanum, Cerium, Praeseodymium, Neodymium, Promethium, Samarium, Europium, Gadolinium, Terbium, Dysprosium, Holmium, Erbium, Thulium, Ytterbium, Lutetium, the fluoride, chloride, bromide, sulfate or nitrate salts or hydrates of the following elements: Cobalt, Nickel, Manganese, Copper, Molybdenum, Vanadium, Zirconium, Chromium, Aluminum, Thorium, Cadmium, Tin, Tantalum, Titanium and Carbon, a noble element or compound thereof, polyvinylchloride or ammonium nitrate.
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