发明名称 PROCESS FOR PRODUCING IMPROVED ABSORBENT POLYMERS BY MEANS OF CRYOGENIC GRINDING
摘要 A process for producing a water-absorbing polymer comprises: (i) mixing (alpha1) 0.1-99.99% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof, or ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, (alpha2) 0-70% by weight of ethylenically unsaturated monomers copolymerizable with (alpha1), (alpha3) 0.001-10% by weight of one or more crosslinkers, (alpha4) 0-30% by weight of water-soluble polymers, and (alpha5) 0-20% by weight of one or more assistants, where the sum of the weights (alpha1) to (alpha5) is 100%; (ii) free-radical polymerization with crosslinking to form an untreated hydrogel polymer; (iii) coarse comminution of the untreated hydrogel polymer to give pieces having a diameter from 0.1 mm to 5.0 cm; (iv) cooling and grinding the untreated hydrogel polymer; (v) drying the untreated hydrogel polymer after grinding at a temperature from 85° C. to 260° C.; (vi) postcrosslinking the hydrogel polymer and (vii) drying the water-absorbing polymer.
申请公布号 US2014045683(A1) 申请公布日期 2014.02.13
申请号 US201113876736 申请日期 2011.10.05
申请人 LOICK CHRISTOPH;GARTZ DOMINIK;WATTEBLED LAURENT;HARREN JORG;EVONIK DEGUSSA GMBH 发明人 LOICK CHRISTOPH;GARTZ DOMINIK;WATTEBLED LAURENT;HARREN JORG
分类号 B01J20/26 主分类号 B01J20/26
代理机构 代理人
主权项
地址