发明名称 Bisamide-zinc bases
摘要 The present invention relates to zinc amide bases of the general formula (I) (R1R2N)2-Zn.aMgX12.bLiX2(I) wherein R1 and R2 are each independently selected from substituted or unsubstituted, linear or branched alkyl, alkenyl, alkynyl or silyl derivatives thereof, and substituted or unsubstituted aryl or heteroaryl, and wherein R1 and R2 can form together a ring structure, or R1 and/or R2 can be part of a polymer structure; X12 is a divalent anion or two monovalent anions that are independent from each other; X2 is a monovalent anion; a is >0; and b is >0. The zinc amide bases can be used, amongst other things, for deprotonation and metallization of aromatics.
申请公布号 US8513416(B2) 申请公布日期 2013.08.20
申请号 US20080599852 申请日期 2008.05.14
申请人 KNOCHEL PAUL;WUNDERLICH STEFAN;LUDWIG-MAXIMILIANS-UNIVERSITAT MUENCHEN 发明人 KNOCHEL PAUL;WUNDERLICH STEFAN
分类号 C07D401/02;C07F3/06 主分类号 C07D401/02
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