MOLECULAR COMPLEXES OF ZINC AND CADMIUM BIS(1-PHENYL-3-METHYL-4-FORMYL-5-PYRAZOLONATE) WITH AMINO-DERIVATIVES OF NITRIC HETEROCYCLES, HAVING LUMINESCENT ACTIVITY

摘要

FIELD: chemistry.SUBSTANCE: invention relates to molecular complexes of zinc and cadmium bis(1-phenyl-3-methyl-4-formyl-5-pyrazolonate) with amino-derivatives of nitric heterocycles of general formula(I) (NH-Het), where NH-Het is 1-aminoisoquinoline, 3-aminoquinoline, 6-aminoquinoline, 5-amino-4,6-dimethylquinoline, 2-aminopyridine, 2-amino-5-bromopyridine, 3-amino-5-methylisoxazole, 2-amino-1-ethylbenzimidazole, M is Zn, Cd, n=1, 2.EFFECT: molecular complexes of formula (I) exhibit luminescent properties in the blue region of the spectrum and can be used as phosphors for making organic light-emitting diodes of white and visible light.14 ex