发明名称 Process for the production of diols
摘要 The invention relates to a process for the production of diols with a special structure which are characterized by formula (I). These diols are substances which, besides two OH groups, contain a C═C double bond so that they are suitable as monomers for the production of polymers. The process comprises hydrolyzing a corresponding cyclic precursor in aqueous medium in the presence of an acid dissolved in that medium, the hydrolysis being accompanied by the elimination of a carbonyl compound, and subsequently neutralizing the acid present in the reaction mixture with a base, the base having a pKb value above 0.18 and preferably above 3.0 and being present in heterogeneous form.
申请公布号 US8334401(B2) 申请公布日期 2012.12.18
申请号 US20080599771 申请日期 2008.05.02
申请人 MCKENNA PETER;SMALLRIDGE MARK;MATTHEWS MELISSA;ROBERTS SIMON;COGNIS IP MANAGEMENT GMBH 发明人 MCKENNA PETER;SMALLRIDGE MARK;MATTHEWS MELISSA;ROBERTS SIMON
分类号 C07C69/52 主分类号 C07C69/52
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