摘要 |
A process for carrying out catalytic hydrogenation reactions involving as three phases a suspended catalyst, the hydrogen-carrying gas and the substance to be hydrogenated travelling in concurrent relationship is characterized in that the heterogeneous mixture is forced through a reaction zone at a flow rate of at least 0.5 metre/sec. The process is described with reference to the hydrogenation of cyclohexene to cyclohexane in the presence of Raney Ni.ALSO:A process for carrying out catalytic hydrogenation reactions involving as three phases a suspended catalyst, the hydrogen-carrying gas and the substance to be hydrogenated travelling in concurrent relationship is characterized in that the heterogeneous mixture is forced through a reaction zone at a flow rate of at least 0.5 metre/second. The process is described with reference to H2O2 from redox of alkyl anthraquinones in the presence of Pd black.ALSO:A process for carrying out catalytic hydrogenation reactions involving as three phases a suspended catalyst, the hydrogen-carrying gas and the substance to be hydrogenated travelling in concurrent relationship is characterized in that the heterogeneous mixture is forced through a reaction zone at a flow rate of at least 0.5 metre/sec. The process is described with reference to (1) the hydrogenation of styrene oxide to b -phenylethylalcohol in the presence of Pt black.ALSO:A process for carrying out catalytic hydrogenation reactions involving as three phases a suspended catalyst, the hydrogen-carrying gas and the substance to be hydrogenated travelling in concurrent relationship is characterised in that the heterogeneous mixture is forced through a reaction zone at a flow rate of at least 0.5 metre/sec. The process is described with reference to (1) the hydrogenation of styrene oxide to -phenylethylalcohol in the presence of Pt black (2) cyclohexene to cyclohexane in the presence of Raney Ni and (3) H2O2 from redox of alkyl anthraquinones in the presence of Pd black. |