摘要 |
The present invention provides novel processes for preparing a fluorinated acyl fluoride and a fluorinated vinyl ether. Namely, it provides a process for preparing a fluorinated acyl fluoride (3), which comprises reacting a compound (1) having a fluorine content of 30 mass% or above with fluorine in a liquid phase to form a compound (2) and then dissociating the ester bond in the compound (2), and a process for preparing a fluorinated vinyl ether (10), which comprises pyrolyzing the fluorinated acyl fluoride: <CHEM> <CHEM> <CHEM> <CHEM> wherein R<A> and R<B> are alkyl groups or the like, or the combination R<A> and R<B> is an ethereal oxygen-containing alkylene group or the like, R<C> and R<D> are perfluoro(ethereal oxygen-containing alkyl) groups or the like, or the combination of R<C> and R<D> is a perfluoro(ethereal oxygen-containing alkylene) group or the like, X<1>, X<2>, X<3>, X<4>, X<5> and X<6> are hydrogen atoms, fluorine atoms or the like, R<AF>, R<BF>, R<CF> and R<DF> are groups derived respectively from R<A>, R<B>, R<C> and R<D> by replacing substantially all of the hydrogen atoms by fluorine atoms. |
申请人 |
ASAHI GLASS COMPANY, LIMITED |
发明人 |
OKAZOE, TAKASHI;WATANABE, KUNIO;ITO, MASAHIRO;SHIRAKAWA, DAISUKE;TATEMATSU, SHIN |