发明名称 |
NOVEL AROMATIC SULFONIC ACID ESTER DERIVATIVE, POLYARYLENE, POLYARYLENE HAVING SULFONIC ACID GROUP AND PROCESS FOR PRODUCING THE SAME, AND POLYMER SOLID ELECTROLYTE AND PROTON-CONDUCTIVE MEMBRANE |
摘要 |
Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1); <IMG> in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, -OSO3CH3 and -OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, R a is a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of -SO3R b (wherein R b is a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.
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申请公布号 |
CA2438009(C) |
申请公布日期 |
2008.07.08 |
申请号 |
CA20032438009 |
申请日期 |
2003.08.22 |
申请人 |
JSR CORPORATION |
发明人 |
ROZHANSKII, IGOR;TAKAHASHI, MASAYUKI;GOTO, KOHEI;KONNO, YOUSUKE;OHTSUKI, TOSHIHIRO;YAMAKAWA, YOSHITAKA;KADOTA, TOSHIAKI |
分类号 |
C07C309/73;C08J5/22;C07C309/75;C07C317/24;C08G61/00;C08G61/12;H01B1/06;H01M8/02;H01M8/10 |
主分类号 |
C07C309/73 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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