摘要 |
Process for the preparation of stable nitroxyl radicals (I) starting from N-benzylphthalimide in two steps. In the first step, the intermediate N-benzyl-1, 1, 3, 3-tetra- alkylisoindoline is prepared by treatment with a Grignard reagent, prepared in methyl-tert-butyl ether, of N- benzylphthalimide, obtained in the same reaction environ - ment starting from phthalic anhydride and benzylamine. In the second step, the N-benzyl-1, 1, 3 , 3-tetra- alkylisoindoline is transformed into the nitroxyl radical by hydrogenolysis and subsequent oxidation with hydrogen peroxide in the presence of a catalyst selected from acids and salts of polymolybdic or polytungstic acids.
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申请人 |
POLIMERI EUROPA S.P.A.;CALDARARO, MARIA;PO', RICCARDO;RICCI, MARCO |
发明人 |
CALDARARO, MARIA;PO', RICCARDO;RICCI, MARCO |