摘要 |
[Subject] To provide a method for effectively producing a triarylsulfonium salt having a structure that only one aromatic ring of three aromatic rings on the cation portion thereof is different from the other two aromatic rings (hereinafter, abbreviated as a triarylsulfonium salt relating to the present invention) in a high yield without forming any byproduct. [Means for Solution Problems] The present invention relates to a method for producing a triarylsulfonium salt represented by the general formula [4]: wherein, two R<SUP>1</SUP>'s represent each hydrogen atom, halogen atom, alkyl group, lower haloalkyl group, alkoxy group, acyl group, hydroxyl group, amino group, nitro group or cyano group; R represents an aryl group which may have a substituent selected from a halogen atom, an alkyl group, a lower haloalkyl group, an alkoxy group, an alkylthio group, a N-alkylcarbamoyl group and a carbamoyl group, and the above substituent is different from one represented by the above R<SUP>1</SUP>; and A<SUB>1 </SUB>represents a strong acid residue, comprising reacting a diaryl sulfoxide represented by the general formula [1]: wherein, R<SUP>1 </SUP>represents the same as above, and an aryl Grignard reagent represented by the general formula [2]: <?in-line-formulae description="In-line Formulae" end="lead"?>RMgX [2]<?in-line-formulae description="In-line Formulae" end="tail"?> wherein, X represents a halogen atom; R represents the same as above, in the presence of an activator with high affinity for oxygen of 3 to 7.5 equivalents relative to the above diaryl sulfoxide, and then reacting the resultant reaction mixture with a strong acid represented by the general formula [3]: <?in-line-formulae description="In-line Formulae" end="lead"?>HA<SUB>1 </SUB> [3]<?in-line-formulae description="In-line Formulae" end="tail"?> wherein, A<SUB>1 </SUB>represents the same as above, or a salt thereof.
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