发明名称 |
METHOD FOR PRODUCING DIMER OR POLYMER |
摘要 |
PROBLEM TO BE SOLVED: To provide a method for production with which the objective substance is inexpensively produced without disposing a manganese peroxidase from the reaction system and the polymerization is carried out by precisely controlling conditions in order to efficiently obtain a specific dimer or a specific polymer in stable yield when a polymerization reaction is conducted by using trivalent manganese obtained by actions of the manganese peroxidase immobilized on a carrier. SOLUTION: The method for producing the dimer or the polymer comprises the following steps: a first step of making an aqueous solvent containing an oxidizing agent and divalent manganese flow through a column filled with the carrier immobilizing the manganese peroxidase and oxidizing the divalent manganese into the trivalent manganese; a second step of measuring the feed rate of the aqueous solvent containing the trivalent manganese to a reactor and the concentration of the trivalent manganese and feeding the aqueous solvent containing the trivalent manganese to the reactor while measuring the feed rate of the trivalent manganese; a third step of feeding a substrate in an amount regulated on the basis of the feed rate of the trivalent manganese to the reactor; and a fourth step of polymerizing the substrate in the presence of the trivalent manganese in the reactor and affording the dimer or polymer. COPYRIGHT: (C)2007,JPO&INPIT
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申请公布号 |
JP2007068516(A) |
申请公布日期 |
2007.03.22 |
申请号 |
JP20050262593 |
申请日期 |
2005.09.09 |
申请人 |
KYUSHU UNIV;DAINIPPON INK & CHEM INC |
发明人 |
WARIISHI HIROYUKI;NONAKA DAISUKE;TERAMAE ATSUSHI;NISHIBASHI HIDEJI;EBARA TAKESHI;IDO YOSHIKO |
分类号 |
C12P7/22 |
主分类号 |
C12P7/22 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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