| 摘要 |
The present invention provides unique material systems and methods for 3D printing of articles having enhanced strength and durability. The powder systems comprise a water-soluble crosslinkable agent, and alternatively or additionally, a strengthening component. Preferably, the crosslinkable agent is selected from the group consisting of amino resins, phenol resins, and mixed amino/phenol resins. The strengthening component melts and flows when heated, and resolidifies or cures. Preferably, the strengthening component melts, flows and cures with heat. In another aspect, the invention provides a powder/binder system comprising an oxidant and a reductant (a redox couple). When the binder is applied to the powder, the oxidant and reductant react to generate an acid that catalyzes crosslinking. As a result, the strength of the 3D article builds up at an enhanced rate. The oxidant may be in the powder, and the reductant in the binder; or the reductant may be in the powder, and the oxidant in the binder. Alternatively, both the oxidant and the reductant may be in the powder.
|
