发明名称 GROUP OF METALLIC GRAIN WITH PROTECTIVE FILM HAVING CONTROLLED GRAIN SIZE AND PRODUCTION METHOD THEREFOR
摘要 PROBLEM TO BE SOLVED: To provide a group of metallic grains with a protective film, which has little variation in grain sizes, and a group of metallic grains with desired grain sizes in the order of nanometers. SOLUTION: Quaternary ammonium salt is added to a two phase system of a chloroauric (III) acid aqueous solution and toluene, and chloroauric (III) ions are moved to a toluene phase. Dodecanethiol is added to the toluene phase, and the chloroauric (III) ions are reduced, and a solvent is removed. The obtained solid matter is heated at a temperature higher than the melting points of dodecanethiol and quaternary ammonium salt and also lower than the boiling points thereof, and the quaternary ammonium salt is thereafter removed.
申请公布号 JP2003049205(A) 申请公布日期 2003.02.21
申请号 JP20010240271 申请日期 2001.08.08
申请人 KANSAI TLO KK 发明人 MIYAKE MIKIO;TERANISHI TOSHIJI
分类号 B22F1/02;(IPC1-7):B22F1/02 主分类号 B22F1/02
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