摘要 |
A method of reducing the formation of coke deposits on the heat-transfer surfaces of an ethylene dichloride to vinyl chloride pyrolysis furnace comprising exposing the heat transfer surfaces of said pyrolysis furnace to a phosphine selected from the group consisting of phosphines with the general formula:wherein R1, R2 and R3 are selected from the group consisting of hydrogen, chlorine, alkyl, aryl, alkylaryl and arylalkyl, wherein R1, R2 and R3 can be the same or different. |