Verfahren zur Herstellung von Polyester

摘要

A process for producing a polyester by preparing a slurry of powdery aromatic dicarboxylic acid in a liquid diol and processing the resulting slurry through an esterification step and a polycondensation step in the presence of a catalyst, comprising recycling a liquid containing unreacted diol and catalyst separated from the reaction mixture in the polycondensation step back to the esterification step as recycling liquor, detecting the concentrations of diol, diol condensation products, catalyst and water in the recycling liquor in the course of being recycled back to the esterification step by a near infrared spectrophotometer of a noise level of at the highest 50 x 10<-6> Abs with a wave length repeatability of 0.01 nm or less as well as by an X-ray fluorescence analyzer and controlling the operation of the reactor based on the detected analytical values in such a manner that the totalized composition of the starting materials supplied to the reaction system and the recycling liquor will be maintained in a predetermined range.