发明名称 |
PRODUCTION OF TRICYCLODECANEDICARBALDEHYDE AND/OR PENTACYCLOPENTADECANEDICARBALDEHYDE |
摘要 |
PROBLEM TO BE SOLVED: To obtain the subject compound at low cost and in high yield by adding an extraction solvent composed of a polyhydric alcohol to a specific reaction product liquid to effect separation into a hydrocarbon compound layer containing a catalyst component and an extraction solvent layer containing the product. SOLUTION: This compound is obtained by such processes that (F) a reaction product liquid containing the objective compound is obtained by hydroformylation of (A) a dicyclopendadiene and/or tricyclopendadiene with (B) hydrogen and (C) carbon monoxide in the presence of a catalyst composed of (i) a rhodium compound and (ii) an organophosphorus compound in (E) a hydroformylation solvent composed of a hydrocarbon compound (e.g. methylcyclohexane), and then (G) an extraction solvent composed of a 2-6C polyhydric alcohol (e.g. ethylene glycol) is admixed into the component F to effect separation into a component E layer containing the component D and a component G layer containing the objective compound. |
申请公布号 |
JP2001011008(A) |
申请公布日期 |
2001.01.16 |
申请号 |
JP19990188687 |
申请日期 |
1999.07.02 |
申请人 |
MITSUBISHI GAS CHEM CO INC |
发明人 |
NAKAMURA KENICHI;YAMADA KAZUHIRO |
分类号 |
B01J31/20;C07B61/00;C07C45/50;C07C45/80;C07C47/347;G02B1/04;G02B6/00;G02C7/02 |
主分类号 |
B01J31/20 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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