| 摘要 |
<p>A process of reacting (A) a compound capable of forming a stable radical which is selected from among (A1) oxygen compounds having carbon-hydrogen bonds at the position adjacent to the oxygen atom, (A2) carbonyl compounds and (A3) compounds having hydrocarbon groups bearing methyne carbon with (B) a radical-scavenging compound selected from among (B1) unsaturated compounds, (B2) compounds having hydrocarbon groups bearing methyne carbon, and so on in the presence of molecular oxygen by the use of an imide catalyst represented by general formula (1) or the like to thereby obtain an adduct of the compound (B) with the compound (A), a product of substitution of the compound (B) with the compound (A), or oxides of both. In said formula, R?1 and R2¿ are each hydrogen or the like, or alternatively R?1 and R2¿ may be united to form a double bond or an aromatic or nonaromatic ring; and X is oxygen or hydroxyl. This process makes it possible to efficiently produce various organic compounds under mild conditions through addition or substitution by the use of molecular oxygen.</p> |
