发明名称 SUPPORTED METALLOCENE CATALYST USED IN OLEFIN POLYMERIZATION REACTION
摘要 PURPOSE: A catalyst is provided to represent a high activation and a high production rate in a copolymerization reaction and in slurry polymerization reaction and in a copolymerization reaction and also in moving gas phase polymerization reaction of olefin. CONSTITUTION: A catalyst contains a carrier, alumoxane and one or more of metallocene and the catalyst is a shape of free-flowing corpuscle, contains a dried power particle having 1-250 micron of an average particle size. The catalyst containing single transition metal as a shape of metallocene has an activation represented kg unit of a polymer of each transition metal 1g. An amount of metallocene in the phase of the carrier is 0.001-10wt% based on the transition metal element. So, the ratio of Al: Zr of the catalyst can be 25-10,000 and generally 70-980. Herein, the carrier material is porous inorganic material such as silicon or oxide of aluminum.
申请公布号 KR20000023611(A) 申请公布日期 2000.04.25
申请号 KR19997000059 申请日期 1999.01.08
申请人 MOBIL OIL CORPORATION 发明人 MINK ROBERT EVAN;NOURIN THOMAS EDWARD;CHISIN YURI VICTOROVICH;ROPREDERIKYIP-KWAI
分类号 C08F4/658;B01J31/22;B01J31/26;C08F4/619;C08F4/6192;C08F4/64;C08F4/76;C08F10/00;C08F110/02;C08F210/16 主分类号 C08F4/658
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