摘要 |
A biaxially-oriented polypropylene film has at least one base layer contg. polypropylene with the following properties: (i) a statistical ave. for the isotactic block length between 2 chain breaks of at least 40; (ii) an n-heptane insols. fraction having a chain-isotacticity index (measured by 13C NMR spectroscopy) of at least 95 (esp. at least 97)%; (iii) an Mw/Mn ratio below 4, esp. below 2.7; (iv) an n-heptane soluble fraction below 1%; and (v) a water vapour transmission no more than 24/micron thickness g/m<2>.d and an O2 transmission no more than 34,000/meter thickness cm<3>/(m<2>.d.bar). Claimed prodn. is by multi-layer melt extrusion, followed by cooling on a roller and orienting at ratios 3-9:1 lengthwise and 4-12:1 transversely. Pref. the film is 4-100 microns thick,being solely of the above polypropylene layer(s) or having its thickness 40-60% made up of such layer(s). Any other layers (on one or both sides of the polypropylene base layer(s) are of polyolefins which can be heat-sealable. The various layers can also contain neutralising agents, stabilisers, antistats and/or anti-blocking agents. Appropriate polypropylene for the base layer(s) is obtd. using metallocene catalysts.
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申请人 |
HOECHST AG, 65929 FRANKFURT, DE |
发明人 |
PEIFFER, HERBERT, DR., 55126 MAINZ, DE;BUSCH, DETLEF, DIPL.-ING., 66740 SAARLOUIS, DE;DRIES, THOMAS, DR., 55270 SCHWABENHEIM, DE |