| 摘要 |
PURPOSE:To provide a solid electrolyte having sufficient conductivity, with an ion including an Li ion as a conductive carrier, solvated and positioned in a site where an ion can be changeable in structure having a skeleton of aluminosilicate. CONSTITUTION:A nonaqeous solvent, having an effective diameter of the hole diameter of aluminosilicate or less and adsorbable to aluminosilicate, is adopted as a solvent. The aluminosilicate is to be an Li-ion change type zeolite. The nonaqueous solvent is ammonia, sulfonyl chloride, and acetonitrile, etc., in concrete, and an aprotic solvent is preferable. X- or Y-type zeolite having a large effective pore diameter, in particular having large Li-ion change quantity, is preferable as zeolite. The shape of zeolite is to be powder, and Li perchlorate, Li iodide, and Li nitric acid are perferable as Li dissolved in a nonaqueous solvent. Since metallic Li is adopted as electrodes 2 and 2' at the time of manufacturing a solid electrolyte and of utilization for a battery, moisture removal or mix prevention in a solid electrolyte are needed. Quartz glass is perferable for a reaction vessel. |
