发明名称 |
Preparation process of high molecular weight polyesters. |
摘要 |
The object is to prepare a high-molecular-weight polyester in such a way that it is possible to make even relatively small amounts of very high molecular weight available in an advantageous manner. This is achieved by preparing a polyester containing an alkenediol by continuing the polycondensation step to a viscosity number of 50 - 140 cm<3>/g and treating the resultant polyester with from 0.001 to 8 % by weight of a free-radical former which decomposes at temperatures in the range from 130 to 350 @C with a half value period of from 5 s to 120 min, and subsequently continuing the polymerisation to the requisite viscosity number. The process according to the invention allows high-molecular-weight polyesters having the desired property profile to be obtained. |
申请公布号 |
EP0615995(A1) |
申请公布日期 |
1994.09.21 |
申请号 |
EP19930121162 |
申请日期 |
1993.12.31 |
申请人 |
GAF-HUELS CHEMIE GMBH |
发明人 |
KLEINE HOMANN, WALTER, DR.;GROSSE-PUPPENDAHL, THOMAS |
分类号 |
C08G63/52;C08F299/04;C08G63/54;C08G63/78;C08G63/88 |
主分类号 |
C08G63/52 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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