ADDITIONSVERBINDUNGEN, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG.

摘要

Addn. cpds. and their salts (I) are claimed, and their prodn. by reaction of polyepoxide(s) of formula (II) with amine(s) (H2NR2)pNH2-pR1 (III) and at least one amine (IV) of formula (IV), R3NHR4, H2N-A-R4, or H2N-Aasterisk-NR3-Aq-R4, in amts. such that 1-99% of the epoxy gps. react with (III) and 99-1% with (IV); opt., the prod. is treated with acid. n = 2-10; R, R3 = H or 1-24C alkyl; X = 2,3-epoxypropyl residue; p = 0-2; R1 = opt. unsatd. 8-24C alkyl; R2 = 1-12C alkylene; Rasterisk forms a heterocyclic ring; R4 = 2-22C opt. unsatd. (poly)nuclear carbo- or hetero-cyclic system(s) (with CH2, O, S, CO, SO, SO2, or NH links), opt. substd. with R5, Hal, OR5, NR5R6 COOR5, CONR5R6, NR5COR6, CN, CF3, or NO2 (R5, R6 = H or 1-24C alkyl), or -R7-NR8R9 (R7 = 2-200C alkylene, opt. O-interrupted, and R8, R9 = H or 1-24C alkyl), or ((CHR10)yNR11)m(CHR10)yNR8R9 (IV) or (CHR10)yN((CHR10)yNR8R9)2 (y = 2-6; m = 1-6; R8, R9, R10, R11 = H or 1-24C alkyl), or R12OR13 (R12 = 2-30C alkylene, opt. interrupted by O or NR13; R13 = H or 1-24C alkyl); A = 1-30C alkylene; Aasterisk = 1-12C alkylene; q = 0 or 1.