摘要 |
A process for recovering titanium dioxide, useful as a white pigment, from ilmenite-type ores comprises digesting the ore with hydrofluoric acid to produce a fluoride salt-containing solution, treating the fluoride salt-containing solution with an alkali metal salt (preferably KCl) to precipitate alkali metal fluotitanate, treating the precipitate with a base to produce hydrated titanium dioxide and alkali metal fluoride, subjecting the alkali metal fluoride to electrodialytic water splitting to produce base and hydrofluoric acid, employing a portion of the base in the precipitate treating step and recycling a portion of the hydrofluoric acid to the digesting step. The hydrated titanium dioxide can be calcined to produce titanium dioxide. |