发明名称 |
Method for manufacture of phthalic anhydride |
摘要 |
A method for the manufacture of phthalic anhydride by the catalytic oxidation of naphthelene or ortho-xylene which comprises contacting a mixed gas consisting of naphthalene or ortho-xylene and a molecular oxygen-containing gas with a catalyst bed comprising a first catalyst packed on the upstream side of the flow of mixed gas and a second catalyst packed on the down-stream side of the flow, wherein the first catalyst has carried on a nonporous inactive carrier a catalytically active component composed of 67 to 90% by weight of titanium dioxide, 9 to 30% by weight of vanadium pentoxide and 0.7 to 3% by weight of a rubidium compound (calculated as Rb2SO4), and the second catalyst has carried on the nonporous inactive carrier a catalytically active component composed of 67 to 94% by weight of titanium dioxide, 5 to 30% by weight of vanadium pentoxide and at least one member selected from the group consisting of 0.1 to 1% by weight of a tin compound (calculated as SnO2) and 0.5 to 3% by weight of a phosphorus compound (calculated as SnO2).
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申请公布号 |
US4469878(A) |
申请公布日期 |
1984.09.04 |
申请号 |
US19820424636 |
申请日期 |
1982.09.27 |
申请人 |
NIPPON STEEL CHEMICAL CO., LTD. |
发明人 |
KANEYASU, MASATAKA;HARA, TADANORI |
分类号 |
B01J23/22;B01J27/198;B01J35/02;C07C51/265;C07C51/31;(IPC1-7):C07D307/89 |
主分类号 |
B01J23/22 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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