REMOVAL OF DISSOLVED ORGANIC MATTER FROM ACIDIC AQUEOUS SOLUTION

摘要

1412056 Acidic solutions IMI (TAMI) INSTITUTE FOR RESEARCH & DEVELOPMENT 27 July 1973 [30 Aug 1972 16 Oct 1972] 35876/73 Heading C1A Dissolved organic matter is removed from an aqueous acidic solution in which the acid and any other solutes are predominantly inorganic, by adding to the solution a first, water-soluble compound which is an aldehyde or oligomer thereof and a second compound capable of polymerizing together with said first compound under acidic conditions, or a precondensate of the first and second compounds, allowing polymerization to occur to form a polymer insoluble in the solution, and recovering a refined acidic solution from the resulting mixture. The solution may also contain dispersed matter which co-precipitates with the formed polymer. In a modification, a non-acidic aqueous solution may be acidulated prior to treatment as above. The first and second compounds may be added successively or simultaneously, and the recovery of the refined solution may be effected by physical separation, e.g. centrifugation, decantation or filtration, or by extraction of the mixture with an organic solvent of limited water-miscibility, separation of the extract and recovery of the refined acidic solution thereof. The first compound may be formaldehyde or a compound capable of liberating formaldehyde; the second compound may be a phenol having at least two unsubstituted ring positions. Liquor resulting from the decomposition of rock phosphate with sulphuric, hydrochloric or nitric acid may be so treated, the first and second compounds or a precondensate thereof may be added to a slurry resulting from the decomposition, or such slurry may first be mechanically treated to separate solid matter and the compounds or precondensate added to the clarified liquor; the clarified liquor may be concentrated before such addition. Liquor obtained by leaching a copper ore, ilmenite, or uranium-containing ore may be similarly treated, as may spent sulphuric acid recovered from reaction with organic materials. Examples relate to the purification of wet-process phosphoric acid using formaldehyde with phenol, with phenol and urea, and with cresylic acid, and using hexamethylene tetramine with phenol.