摘要 |
An attrition-resistant, unsupported catalytic sulfide containing Nb, Ta, Mo, W, Tc, or Re is used for preparing C1-10 aliphatic hydrocarbons or C1-10 mixed alcohols from synthesis gas. The catalytic sulfide is prepared by precipitating a centric particulate precursor, preferably (NH4)2MoS2O2, and then thermally decomposing the precursor. The catalytic sulfide can optionally have a metal promotor. |