| 摘要 |
Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: <IMAGE> (1) wherein: X and Y are independently O or S; R1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms; an amino or aryl radical; R2 is an alkyl radical having 1 to 6 carbon atoms; R3 is a radical of the general formula: -J-(K-L)n (2) wherein: J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring; K is one of the following radicals: <IMAGE> (3) <IMAGE> (4) <IMAGE> (5) <IMAGE> (6) O (7) linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R4 is hydrogen, an aryl radical, or an alkyl radical of 1 to 6 carbon atoms; L is a halogenated alkyl or alkenyl radical; an alkyl radical (having 1 to 4 carbon atoms) or aryl radical substituted with a vinylsulphonyl group, vinylsulphonamido group or precursors thereof; or a heterocyclic radical containing 1 to 4 halogen atoms attached to carbon atoms adjacent to a nitrogen atom of the ring, the ring being linked directly to K or through an alkylene group having 1 to 4 carbon atoms; n is 1 to 3.
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