Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom

摘要

Metal oxide superconductor powder precursors are prepared in an aerosol pyrolysis process. A solution of the metal cations is introduced into a furnace at 600 DEG -1000 DEG C. for 0.1 to 60 seconds. The process produces micron to submicron size powders without the usual loss of the lead stabilizer. The resulting powders have a narrow particle size distribution, a small grain size, and are readily converted to a superconducting composition upon subsequent heat treatment. The precursors are placed in a metal body deformed to form a wire or tape and heated to form a superconducting article. The fine powders permit a substantial reduction in heat treatment time, thus enabling a continuous processing of the powders into superconducting wire, tape or multifilamentary articles by the powder-in-tube process.