摘要 |
An aminoalkyl imidazolines of the formula:;;having p-octyloxy-, p-dodecyloxy-, or p-octadecyloxy-phenyl pendants as hydrophobes, for use to mitigate mild steel corrosion. An electron-rich aromatic ring, in conjugation with an amidine motif, imparts increasing corrosion inhibition efficiencies with an increasing hydrophobe chain length. X-ray photoelectron spectroscopy confirms the formation of an aminoalkyl imidazoline film on a metal surface prior to reaching a critical molar concentration. |
主权项 |
1: A corrosion inhibiting composition comprising an aminoalkyl imidazoline of formula (I) wherein m is an integer of 1 to 10; R is a C1-C6 alkylene; R1 is selected from the group consisting of aromatic hydrocarbons of formula (II) further wherein X is a heteroatom independently selected from the group consisting of oxygen, and sulfur; R′1 thru R′5 are each independently selected from the group consisting of hydrogen, C1-C30 alkyl, alkenyl, aryl, alkylaryl, arylalkyl, aminoalkyl, and aminoaryl; R2 and R3 and are each independently selected from the group consisting of hydrogen, hydroxyl, halogen, C1-C30 alkyl, alkenyl, aryl, alkylaryl, arylalkyl, aminoalkyl, aminoaryl, (CH2)2COOH, CH2CH(CH3)COOH, and imidazoline. |