主权项 |
1. A method of manufacturing a transparent conductive layer, the method comprising:
a) forming a conductive nanowire layer on a base material; b) thermally treating the conductive nanowire layer; c) applying a conductive metal ink on the conductive nanowire layer; and d) subsequently thermally treating the base material applied with the conductive metal ink to electrically bridge the conductive nanowires with each other by conductive metal particles formed from the conductive metal ink, wherein the conductive metal ink is a conductive metal ink solution containing a silver complex prepared by reacting at least one silver compound selected from the following Chemical Formula 1 and at least one ammonium carbamate-based compound or ammonium carbonate-based compound selected from the following Chemical Formulas 2 to 4:
AgnX (Chemical Formula 1) (n is an integer of 1 to 4, and X is a substituent selected from a group consisting of oxygen, sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, chlorate, perchlorate, tetrafluoroborate, acetylacetonate, carboxylate, and a derivative thereof) (R1, R2, R3, R4, R5, and R6 are each independently a substituent selected from a group consisting of hydrogen, an aliphatic or cycloaliphatic (C1-C30) alkyl group, an aryl group, an aralkyl group, an (C1-C30) alkyl group substituted by a functional group, an aryl group substituted by a functional group, a polymer compound group, a hetero ring compound, and a derivative thereof, or R1 and R2, and R4 and R5 are each independently connected to alkylene with or without heteroatoms to form a ring). |