ANODE COMPOSITE MATERIAL FOR LITHIUM ION BATTERY AND PREPARATION METHOD THEREOF

摘要

Disclosed are an anode composite material for lithium ion battery and a preparation method thereof. The composite material is a composite material formed by compounding at least one of SiCO, SiCNO, SiCN and SiBCN with LiaMbPO4, wherein 0.95 <= a <= 1.1, 0.95 <= b <= 1.1, and M is at least one of Fe, Co, Ni and Mn. The content of at least one of SiCO, SiCNO, SiCN and SiBCN in the anode composite material is in a range of 1-20 wt% of the total weight of the composite material. The composite material formed by compounding at least one of SiCO, SiCNO, SiCN and SiBCN with LiaMbPO4 is obtained by adding LiaMbPO4 into at least one organosilicon polymer of polysiloxane, polysilazane, and polyborosilazane, and then curing, crosslinking, and pyrolysing. Compared with LiaMbPO4, the composite material has a notable improvement in electrochemistry performance and tap density.