主权项 |
1. A compound comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings, said compound having a formula selected from the group consisting of: M is any element selected from the group consisting of Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Ti, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Ti, Si, Ge, Sn, Pb, P, As, Sb, Bi, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, and U; wherein R1, R3-R5, R7-R8 and R51-R82 are independently selected from the group consisting of hydrogen, alkyl, fluoroalkyl, hydroxyl, halo, mercapto group, amino, cyano, alkenyl, alkynyl, and aryl, wherein R2 and R6 are independently selected from the group consisting of hydrogen, alkyl, fluoroalkyl, hydroxyl, alkoxy, halo, mercapto group, amino, cyano, alkenyl, alkynyl, 3,5-di-tert-butylphenyl, and aryl, and wherein adjacent substituents R51-R82 optionally form fused rings, wherein the fused rings are aromatic, unsaturated, or combinations of both aromatic and unsaturated rings, including four, five, six, seven, eight, or nine-membered rings, wherein the fused rings can include one or more heteroatoms independently selected from the group consisting of O, S, Se, Te, N, P, As, Si, Ge, and B. |